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Buy Polyglyceryl-4 Oleate

Polyglyceryl-4 Oleate is a natural, plant-based emulsifier derived from sunflower seed oil and vegetable glycerin. Specially designed as a low HLB emulsifier, it is ideal for creating water-in-oil (W/O) emulsions, cleansing oils, and balm-to-milk formulations.

 Polyglyceryl-4 Oleate is 100% natural, COSMOS and NATRUE certified, vegan, palm-free, and cruelty free, making it a globally accepted choice, It’s a versatile option for formulators looking to create mild, skin-friendly products with a natural profile.

Polyglyceryl-4 Oleate is also a gentle co-emulsifier for oil-in-water (O/W) emulsions and works as an emollient, adding softness and moisturisation to skincare, haircare, and cosmetic products.

How we use Polyglyceryl-4 Oleate

  • Water-in-oil creams and lotions
  • Cleansing oils and balm-to-milk cleansers
  • Anhydrous formulations that self-emulsify on contact with water
  • Sun care and after-sun emulsions
  • Colour cosmetics such as sticks, balms, and foundations
  • Deodorants and shaving creams
  • Hair conditioners and treatment oils
  • Bath oils and emulsifying blends

Polyglyceryl-4 Oleate Specifications

INCI Name: Polyglyceryl-4 Oleate
CAS Number: 9007-48-1 
EINECS Number: 618-437-6
Form: Cloudy viscous liquid
Scent: Mild
pH Stability: 6.5 – 7.5
HLB Value: 4 – 6
Solubility: Oil-soluble, dispersible in water
Usage Rate: Emulsifier 1–5%, Emollient 5–12% (up to 15% in some applications)
Origin: Plant-based from sunflower oil & vegetable glycerin

How to formulate with Polyglyceryl-4 Oleate

  • Add to the oil phase of your formulation (hot or cold process).
  • Stir before use to ensure homogeneity.
  • Use as a primary emulsifier for water-in-oil emulsions (no co-emulsifier needed).
  • Can also be used as a co-emulsifier in oil-in-water emulsions for added stability.
  • Works well in balm-to-milk cleansers and self-emulsifying products.

Tips & Formulation Notes

  • Creates very mild, skin-friendly cleansing products, though rinse-off is gentler compared to emulsifiers like Polysorbate 80 or PEG-40 Hydrogenated Castor Oil.
  • Ideal for sensitive skin formulations and natural product lines.
  • Store in a cool, dark, and dry place. 
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Polyglyceryl-4 Oleate (Emulsifier)

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Buy Polyglyceryl-4 Oleate

Polyglyceryl-4 Oleate is a natural, plant-based emulsifier derived from sunflower seed oil and vegetable glycerin. Specially designed as a low HLB emulsifier, it is ideal for creating water-in-oil (W/O) emulsions, cleansing oils, and balm-to-milk formulations.

 Polyglyceryl-4 Oleate is 100% natural, COSMOS and NATRUE certified, vegan, palm-free, and cruelty free, making it a globally accepted choice, It’s a versatile option for formulators looking to create mild, skin-friendly products with a natural profile.

Polyglyceryl-4 Oleate is also a gentle co-emulsifier for oil-in-water (O/W) emulsions and works as an emollient, adding softness and moisturisation to skincare, haircare, and cosmetic products.

How we use Polyglyceryl-4 Oleate

  • Water-in-oil creams and lotions
  • Cleansing oils and balm-to-milk cleansers
  • Anhydrous formulations that self-emulsify on contact with water
  • Sun care and after-sun emulsions
  • Colour cosmetics such as sticks, balms, and foundations
  • Deodorants and shaving creams
  • Hair conditioners and treatment oils
  • Bath oils and emulsifying blends

Polyglyceryl-4 Oleate Specifications

INCI Name: Polyglyceryl-4 Oleate
CAS Number: 9007-48-1 
EINECS Number: 618-437-6
Form: Cloudy viscous liquid
Scent: Mild
pH Stability: 6.5 – 7.5
HLB Value: 4 – 6
Solubility: Oil-soluble, dispersible in water
Usage Rate: Emulsifier 1–5%, Emollient 5–12% (up to 15% in some applications)
Origin: Plant-based from sunflower oil & vegetable glycerin

How to formulate with Polyglyceryl-4 Oleate

  • Add to the oil phase of your formulation (hot or cold process).
  • Stir before use to ensure homogeneity.
  • Use as a primary emulsifier for water-in-oil emulsions (no co-emulsifier needed).
  • Can also be used as a co-emulsifier in oil-in-water emulsions for added stability.
  • Works well in balm-to-milk cleansers and self-emulsifying products.

Tips & Formulation Notes

  • Creates very mild, skin-friendly cleansing products, though rinse-off is gentler compared to emulsifiers like Polysorbate 80 or PEG-40 Hydrogenated Castor Oil.
  • Ideal for sensitive skin formulations and natural product lines.
  • Store in a cool, dark, and dry place. 

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